Prokofiev Akinfievich Demidov (1710-1786) - philanthropist and patron, the guardian of the Moscow-education house, where he founded later a Commercial College in1772. Levitsky skillfully uses the language of allegory to translate the idea of educating people into people potential of doing public good. Demidov is depicted in the casual attire, which is very unusual for a parade style of portrait, and rather represents that the character is not in serves and does not have titles. With right hand he points to the flowering plants and the building of the Education House, inhabitants of which, just as flowers, are in need of care.

In the portrait of Mary Alexeevna Djakova (1755-1807), daughter of the chief prosecutor of the Senate, A. Djakova, embodied as an aesthetic ideal of the Education. Djakova, later wife of artist's friend, architect N. Lvov, was richly talented artistic person. She wrote poems and sang beautifully. Even after being married, she posed for Levitsky.

Countess Ursula Mniszek (about 1750-1808) - a brilliant example of aristocracy, State Russian court lady, the sister of the last Polish king Stanislaw August Poniatowski. Oval shape of the portrait, masterfully used by Levitsky to portray the Countess, even this style is unusual for the artist.

Agafya Dmitrievna, by marriage Andreyeva (1760th - 1805) - daughter of the artist. An interest to the national folk topic becomes popular in Russia in the second half of XVIII century as a character (nature) of this fashionable folk excitement. Levitsky was drawn to this genre of costume portrait, depicts his leading lady in Russian festive attire.